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Chemical Compatibility

Plug Valve — Acids

Strong evidence

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Named chemicals

Hydrofluoric Acid (dedicated HF4D/Tertiary Top Seal line)Sulfuric AcidAcetic AcidPhosphoric Acid

What LibertyCES's vendor documentation shows

Dedicated HF-service product variants (Low Emission HF4D, Tertiary Top Seal) endorsed by UOP/ConocoPhillips for HF Alkylation Units.

Materials documented for this service

  • Sleeve materials undisclosed ("upon request")
  • Carbon Steel/CF8M/Nickel Alloys body

Products cited for this service

Crane CPE/XOMOX Sleeved Plug Valve — HF4D, Tertiary Top Seal (Hydrofluoric)

Real Specifications

Low Emission HF4D size & rating1/2"-12", Class 300, -20°F to 500°F, first soft-seated sleeved plug valve meeting ISO 15848-1 AND API 641 with zero packing adjustments during thermal cyclingcrane-cpe-xomox-sleeved-plug-valves.md
Tertiary Top Seal endorsementDesign listed/approved by UOP and ConocoPhillips Petroleum Company for HF Alkylation Units, Class 300 & 600 DR, EPA Method 21 + API 607 certifiedcrane-cpe-xomox-sleeved-plug-valves.md
Barstock named chemistry listExplicit chemistry list includes sulfuric acid, hydrochloric acid, acetic acid, caustics; sizes 1/2"-2", Class 150/300/600, -20°F to 600°Fcrane-cpe-xomox-sleeved-plug-valves.md
SR named applicationSulfuric Acid Alkylation explicitly named, meets API 641 with zero packing adjustments across 3 thermal cyclescrane-cpe-xomox-sleeved-plug-valves.md
Install / Failure Note

HF4D's 4th sealing barrier (4D stem packing) and HF Detection Paint option exist because an undetected HF leak is a serious safety event — a real, named leak-detection feature specific to hydrofluoric acid alkylation service, not a generic accessory.

UOP and ConocoPhillips approving the Tertiary Top Seal's design for HF Alkylation Units is a named-customer engineering endorsement that doesn't appear anywhere else in this vendor's catalog — on a chemistry where an undetected leak is a real safety event, that's worth more than a pressure rating alone.

Every material and product claim on this page traces to real, vendor-published documentation on file with LibertyCES. Chemical compatibility depends on exact concentration, temperature, and duty cycle — confirm current specifications with the manufacturer and request a spec review before final specification.

FAQ

Is Plug Valve compatible with Acids?

Dedicated HF-service product variants (Low Emission HF4D, Tertiary Top Seal) endorsed by UOP/ConocoPhillips for HF Alkylation Units. This is strong evidence.

What materials are documented for Plug Valve in Acids service?

Materials documented for this service: Sleeve materials undisclosed ("upon request"), Carbon Steel/CF8M/Nickel Alloys body. Chemical compatibility depends on exact concentration, temperature, and duty cycle — confirm with a spec review before final specification.

What specific Acids chemicals does this cover?

Named chemicals in this documentation: Hydrofluoric Acid (dedicated HF4D/Tertiary Top Seal line), Sulfuric Acid, Acetic Acid, Phosphoric Acid.

What products are cited for Plug Valve in Acids service?

Documented examples include Crane CPE/XOMOX Sleeved Plug Valve — HF4D, Tertiary Top Seal (Hydrofluoric).

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