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Chemical Compatibility

Controller — Acids

Multi-source documented

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Named chemicals

Sulfuric Acid (chrome reduction/cyanide destruction stage 2)
Direct answer

LibertyCES has documented Controller in Acids service, including Sulfuric Acid. Documented models include GF Signet controller. Compatibility depends on exact concentration, temperature and duty cycle, so confirm with a free spec review.

Notes from the vendor documentation

Chrome reduction: pH lowered to 2.0-2.5 via acid dosing, ORP setpoint -300mV, explicit SO2 gas-release hazard if overdosed.

Materials documented for this service

  • N/A

Products cited for this service

GF Signet controller

Real Specifications

SpecValueSource document
Chrome reduction optimum pH rangepH 2.0-2.5GF Piping Systems — Application Solutions Made Easy: Chemical Process Industry
Chrome reduction minimum detention time15 minutesGF Piping Systems — Application Solutions Made Easy: Chemical Process Industry
Chrome reduction ORP setpoint-300mV (-400mV max)GF Piping Systems — Application Solutions Made Easy: Chemical Process Industry
Cyanide destruction stage 2 (sulfuric acid) detention timeUp to 4 hours (modern systems)GF Piping Systems — Application Solutions Made Easy: Chemical Process Industry
Cyanide destruction stage 1 oxidation targetBelow 0.1 ppmGF Piping Systems — Application Solutions Made Easy: Chemical Process Industry
Install / Failure Note

GF Signet warns explicitly that lowering pH further than the 2.0-2.5 optimum on chrome reduction risks releasing hazardous sulfur dioxide gas — the reaction only needs to reach pH 3.0 before it slows significantly, so overshooting low doesn't buy faster reduction, it buys a gas hazard.

Chrome reduction is regulatorily strict for a reason — hexavalent chromium is roughly a thousand times more toxic than trivalent chromium per GF Signet's own literature, and it won't form a settleable hydroxide precipitate until it's reduced. Getting the pH/ORP control loop right (2.0-2.5 pH, -300mV ORP, 15-minute minimum detention) is the difference between a compliant discharge and a violation, which is why Liberty CES treats this controller spec as safety-critical rather than a tuning nicety.

Every material and product claim on this page traces to real, vendor-published documentation on file with LibertyCES. Chemical compatibility depends on exact concentration, temperature, and duty cycle — confirm current specifications with the manufacturer and request a spec review before final specification.

FAQ

Can Controller handle Acids?

Chrome reduction: pH lowered to 2.0-2.5 via acid dosing, ORP setpoint -300mV, explicit SO2 gas-release hazard if overdosed.

What wetted materials should Controller use in Acids service?

Materials documented for this service: N/A. Compatibility depends on exact concentration, temperature and duty cycle, so confirm with a spec review before final specification.

Which Acids chemicals does this cover?

Named chemicals in this documentation: Sulfuric Acid (chrome reduction/cyanide destruction stage 2).

Which Controller models are documented for Acids?

Documented examples include GF Signet controller.

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Reviewed by James Riggins, 30+ years specifying water and chemical process equipment · Updated